So called 'natural' colours are not that natural if you ask me - especially if they are intended to lighten the hair. They will need to contain a certain amount of manmade chemicals to create a blonde shade.
I would recommend that your sister speaks to her colourist to see if they would be able to apply some highlights to the hair with a gentle pre lightener. Highlights shouldn't touch the scalp and so in theory are relatively safe. Purple shampoos made to neutralise brassy blonde hair would also be helpful in minimising the ginger colour she is seeing right now.